| Abstract |
Various iron carbonyl clusters such as Fe2(CO)9 or [Et3NH][HFe3(CO)11] are shown to catalyze the dehydration of amides into the corresponding nitriles in the presence of silanes in high yields; this novel protocol showed good functional group tolerance and wide substrate scope. |
| Authors | Shaolin Zhou, Daniele Addis, Shoubhik Das, Kathrin Junge, Matthias Beller |
| Journal | Chemical communications (Cambridge, England)
(Chem Commun (Camb))
Issue 32
Pg. 4883-5
(Aug 28 2009)
ISSN: 1364-548X [Electronic] England |
| PMID | 19652813
(Publication Type: Journal Article)
|
| Chemical References |
- Amides
- Nitriles
- Organometallic Compounds
- Silanes
- Iron
|
| Topics |
- Amides
(chemistry)
- Catalysis
- Dehydration
- Iron
(chemistry)
- Molecular Structure
- Nitriles
(chemistry)
- Organometallic Compounds
(chemistry)
- Silanes
(chemistry)
|
