Abstract |
A new strategy for nereistoxin-related insecticide, cartap, detection in foodstuff and the environment is of great importance due to its poisoning of human beings through direct exposure or via biomagnification. Herein, a highly planar conjugated sp2 carbon-connected COF (F-Csp2-TT) was synthesized via Knoevenagel condensation reaction followed by the post-modification to develop a new platform for cartap visual detection in agricultural and food samples. The synergistic effect of highly planar conjugation and dense functional groups in the opened framework endowed F-Csp2-TT with a high-precision luminescence sensing performance. Meanwhile, the exquisitely designed F-Csp2-TT presented robust chemical stability, radiation stability, and good reproducibility. Benefiting from these advantages, high-precision luminescent F-Csp2-TT achieves a low detection limit of 0.51 μg/L to cartap over the range of 1-300 μg/L (R2=0.9938), and the recoveries percentage in food products was calculated as 95.90%- 119.3%. More significantly, the smartphone-based high-precision platform by F-Csp2-TT was established and successfully applied to portable monitoring of cartap and water content. Therefore, our work revealed the enormous potential of Csp2-connected COF, which opened a new situation for insecticide detection.
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Authors | Ying Zhang, Huilin Liu, Baoguo Sun |
Journal | Journal of hazardous materials
(J Hazard Mater)
Vol. 448
Pg. 130866
(04 15 2023)
ISSN: 1873-3336 [Electronic] Netherlands |
PMID | 36753911
(Publication Type: Journal Article, Research Support, Non-U.S. Gov't)
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Copyright | Copyright © 2023 Elsevier B.V. All rights reserved. |
Chemical References |
- Insecticides
- Metal-Organic Frameworks
- carbamothioic acid, S,S'-(2-(dimethylamino)-1,3-propanediyl) ester
- nereistoxin
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Topics |
- Humans
- Insecticides
(analysis)
- Metal-Organic Frameworks
(chemistry)
- Luminescence
- Reproducibility of Results
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