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m-Terphenyl thiols: rigid and bulky molecules for the formation of bioactive self-assembled monolayers on gold.

Abstract
The m-terphenyl 4-mercaptomethyl-2,6-diphenylbenzoic acid (3), was prepared and shown to form omega-carboxyl terminated self-assembled monolayers (SAMs) on gold with high surface pKa(10.1 +/- 0.2) and low density favourable for the binding of biological macromolecules.
AuthorsDiane A Dickie, Andy Y C Chan, Hanifa Jalali, Hilary A Jenkins, Hua-Zhong Yu, Jason A C Clyburne
JournalChemical communications (Cambridge, England) (Chem Commun (Camb)) Issue 21 Pg. 2432-3 (Nov 07 2004) ISSN: 1359-7345 [Print] England
PMID15514801 (Publication Type: Journal Article, Research Support, Non-U.S. Gov't)
Chemical References
  • Benzoates
  • Organometallic Compounds
  • Sulfhydryl Compounds
  • m-terphenyl 4-mercaptomethyl-2,6-diphenylbenzoic acid
  • Gold
Topics
  • Absorptiometry, Photon
  • Benzoates (chemical synthesis, chemistry)
  • Gold (chemistry)
  • Hydrogen-Ion Concentration
  • Models, Molecular
  • Molecular Structure
  • Organometallic Compounds (chemistry)
  • Sulfhydryl Compounds (chemical synthesis, chemistry)
  • Surface Properties

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